醚后C4制1-丁烯成套技术及工业应用

打开文本图片集

中图分类号：TQ03-39；TE65 文献标志码：A 文章编号：1671-0460（2026）01-0227-08

Abstract： A set of 60kt⋅a-1 1. butene production plant was built by using C4 containing rich 2-butene ether after etherificationasrawmaterial，andadoptingacompletesetof technologypioneeredinChina，namely“selective hydrogenation + superpre-fractionation +2 -butene isomerization+etherificationandisobutylene removal + precision rectification". The operating results showed that under fulload conditions， the total yield of1-butene was 56.15% the average conversion rate of 2-butene in the isomeric unit reached 17.73% ，and the selectivity of 1-butene reached 99.75% ，the loss rates of 1-butene of pre-hydrogenation and post-hydrogenation were 10.22% and 3.46% ，the comprehensive energy consumption was 23359.84MJ-1 .The products1-butene，isobutane，and MTBE met the quality requirements.

Keywords：Chemical reaction;Multiphase reaction;Hydrogenation;Catalysts;Fix-bed;Reactive distillation;

Extraction; Selectivity.

1-丁烯是用途广泛的有机化工产品，主要来源于炼厂乙烯生产装置或催化裂化（裂解）装置副产的 C4 馏分、乙烯二聚产物以及煤制烯烃副产的 C4 组分[1-2]。（剩余7561字）