基于单质硫合成功能性含硫聚合物的研究进展

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中图分类号：TQ316.32；O633.3 文献标志码：A 文章编号：1671-0460（2026）01-0161-08

Abstract： The introduction of sulfurinto polymer backbone can not only improve the properties of many polymers，such as self-healing properties，adsorptionofheavy metalions，etc，but alsosolvetheproblemofserioussulfuraccumulation， which is a very promising method for depleting sulfur.I this paper，the basic principles ofsynthesis ofsulfur-containing polymers by sulfur were introduced based on the three mechanisms of elemental sulfur ring-opening includingfree radical mechanism above a certain temperature，nucleophilic mechanismand electrophilic mechanism.The research progressof preparationofsulfur-containing polymers by inverse vulcanization ofunsaturated compounds and sulfur and the multi-component polymerization methodof amine-catalyzed mechanism was discussed.The advantages and disadvantages of various processes for the synthesis of sulfur-containing polymers based on elemental sulfur were summarized. Finally， the future research direction was prospected.

Key Words： Sulfur; Polymers; Inverse vulcanization; Synthesis;Adsorption; Petroleum; Environment; Radical; Waste water

硫是化石燃料中含量第三高的元素，也是石油和天然气工业的主要副产物之一。（剩余19815字）