金属有机骨架材料的规模化制备方法研究进展

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引用格式：，等. 金属有机骨架材料的规模化制备方法研究进展[J]. 当代化工，2026,55（4）：957-963.

YUAN Jinqiu, YANG Yongjiu, HAO Wenyue, et al. Research Progress in Scalable Preparation Methods for Metal-Organic Frameworks[J]. Contemporary Chemical Industry, 2026, 55(4): 957-963.

1 ， 2 ，郝文月 1 ，郭俊辉 1 ，刘汉邦 1 ，刘昶 1 ，王凤来 1 ，彭绍忠 1

（1. 中石化石油化工研究院有限公司，辽宁 116045；

2. 盛虹炼化有限公司，江苏 222065）

中图分类号：TQ028

文献标志码：A

文章编号：1671-0460（2026）04-0957-07

Research Progress in Scalable Preparation Methods for Metal-Organic Frameworks

YUAN Jinqiu 1 , YANG Yongjiu 2 , HAO Wenyue 1 , GUO Junhui 1 , LIU Hanbang 1 , LIU Chang 1 , WANG Fenglai 1 , PENG Shaozhong 1

Sinopec (Dalian) Research Institute of Petroleum and Petrochemicals Co., Ltd., Dalian Liaoning 116045, China; 2. Shenghong Refining & Chemical (Lianyungang) Co., Ltd., Lianyungang Jiangsu 222065, China)

Abstract: Metal-organic frameworks (MOFs) are an emerging class of crystalline porous materials featuring exceptionally high porosity and highly designable pore structures, which hold strong potential for a wide range of applications such as adsorption, separation, and catalysis. However, industrial manufacturing of MOFs remains challenging due to long reaction time, high solvent consumption, and difficulty in continuous synthesis. In this paper, a variety of promising synthetic routes for large-scale synthesis of MOFs were summarized, the basic principles of process intensification, product structures, and applicable scopes of different energy input methods such as mechanochemistry, electrochemistry, microwave, and ultrasound were reviewed. Finally, the core challenges and future development opportunities in the field of large-scale preparation of MOFs were summarized and prospected.

Keywords: Metal-organic frameworks; Mechanochemistry; Electrochemistry; Microwave-assisted approach; Ultrasonic method

金属有机骨架(MOFs)是一类由金属离子或金属簇与多齿有机配体通过配位键桥连、自组装形成的晶态多孔材料[1-2]。（剩余21356字）