高氯酸铵和黑索金对硝酸羟胺基电控固体推进剂性能的影响

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中图分类号：V512 文献标志码：A

DOI： 10. 7652/xjtuxb202605009 文章编号：0253-987X（2026）05-0091-11

Effects Ammonium Perchlorate RDX on the Performance Hydroxylammonium Nitrate-Based Electrically Controlled Solid Propellants

YANG Meng1，HUANG Wanting1，FANG Ming1，CAI Jiajun1，HUANG Yin2 ， LI Men³，TANG Chenglong'，HUANG Zuohua¹

（1.SchoolEnergy Enginering，Xi'an University，Xi'an71oo49，China；2.Hubei Institute

，Xiangyang，Hubei 4410ol，China；3. Center for

Ammunition Support Education，Army University PLA，Shijiazhuang O5ooo，China）

Abstract： To enhance the energy， conductivity， ignition/combustion characteristics hydroxylammonium nitrate （HAN）-based electrically controlled solid propellants （ECSPs），different ECSP formulations are prepared using ammonium perchlorate （AP） research department explosive（RDX） as additives. NASA CEA is employed to calculate compare the theoretical specific impulse combustion temperature four HAN-based ECSP formulations. The electrical conductivity the four samples was studied using AC impedance spectroscopy， while their thermal decomposition processes were investigated using synchronous thermal analysis. Combustion experiments were conducted under a voltage 200V to determine the ignition delay time burning rate. The results indicate that the addition AP or RDX increases both the theoretical specific impulse combustion temperature the propellant samples，while also raising the heat release reducing the activation energy the thermal decomposition reaction. In terms electrical conductivity，the addition AP increases the conductivity the propellnt，whereas the addition RDX reduces it，with conductivity further decreasing as the RDX content increases. Regarding combustion performance，the baseline formulation exhibits an ignition delay time 4.95 s a burning rate 0.35mm/s . The addition 10% AP shortens the ignition delay time increases the burning rate. The sample with 10% RDX shows earlier ignition a slight improvement in burning rate. However，the sample with 20% RDX experiences ignition dificulties， its burning rate drops to the lowest value. Furthermore，as the voltage increases，the ignition delay time all four samples decreases， the burning rate increases.

Keywords：hydroxylammonium nitrate；electronically controlled solid propellant；electrical conductivity; thermal decomposition；combustion performance

固体火箭发动机凭借结构简洁、体积小巧、维护便捷、使用成本低廉以及可长期储存等优势，在各类精准制导装备和姿态控制系统中得到了广泛应用。（剩余16087字）