微反应器内传质和反应过程强化的研究进展

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文章编号:1003-9015(2026)01-0010-15

中图分类号:TQ052.5 文献标志码:A DOI: 10.3969/j.issn.1003-9015.2025.00.022

Research progress on process intensification of mass transferandreactioninthemicroreactors

QI Yabing, ZHAO Yajuan, Munaiwaier·Tuerxun , ZHANG Sijing (School of Chemistry and Chemical Engineering, Xi'an Universityof Architecture and Technology,Xi'an 710055,China)

Abstract:Microreactors have been widely applied in many fields such as chemical,pharmaceutical, environmental,materials,metalurgy,energy,and medical diagnosis industries due to these advantages,for example,smallvolume,high heat and masstransfer performances,high security,and good controllability. Therein,the global researchers have always focused on intensification of mass transfer and reaction in the microreactors.The structure of microreactors,the enhancements of ultrasonic field,centrifugal field,magnetic field,light and stir have been systematically reviewed. Then,the reasons of intensification of masstransfer and reaction in the microreactors havebeen in-depth analysis.Finally,thedevelopment trends on intensificationof mass transfer and reaction in the microreactors have been prospected.In order to enhance masstransfer and reaction in the microreactors,the folowing measures may be taken:(1) The formation mechanism of droplets, liquid slugs, liquid flows,bubbles,gas slugs and gas flows,and afecting factors and transformation mechanism offluid flow patern in the microreactors have been in-depth-study.(2)The satisfactory reinforcement effect will achieve by using the coupling measures.For example,integration ofspiral microchannels and ultrasonic field,combination of spiral microchannels and photocatalysis,and integration of gas stir and rotating microchannels.(3)The performance optimization and improvement of microreactors have been realized through numerical simulation, experimental study,and scale-up process.The ultimate aim is the application of microreactors in industrial production.

Key words: microreactors; microchannels; microscale; mass transfer;process intensification

1前言

微反应器亦称微通道反应器或微结构反应器,是一类以石英玻璃、高分子材料、无机非金属材料、半导体材料、金属材料等为基材,应用光刻、电铸、塑铸、等离子体加工、电子束加工、微细电火花加工、化学蚀刻、微精密机械加工、3D打印等技术制成微反应空间;或利用毛细管及构件的间隙、材料的微孔等形成微反应空间;或以Pickering乳液滴构筑微反应空间,特征尺寸为 的微型反应器[1-5]。(剩余27612字)

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